Advanced Heat Treatment Process for Nickel-Rich Batteries in Electric Vehicles


The world of electric vehicles (EVs) is rapidly evolving, specifically with developments in battery technology. A significant advancement in this area is the development of nickel-rich chemistries for EV batteries. This article discusses the heat treatment process that contributes to enhancing the performance and longevity of these batteries, marking a significant step forward in EV technology.

High nickel-content batteries have emerged as a front-runner in the development of more efficient and performant EV batteries. These types of batteries are preferred for their higher energy densities, which translates to longer coverable distances on a single charge, and shorter charging times. Nickel-rich batteries, with the most known chemistries being primarily Nickel-Manganese-Cobalt (NMC), and Nickel-Cobalt-Aluminium (NCA), are crucial in the growth of this industry. These materials show also better performance with an increase energy storage capacity and offer longer life cycles. 

The high nickel content can however also lead to technical issues such as rapid capacity loss and increased vulnerability to temperature fluctuations. High temperatures can lead to chemical instabilities, causing safety concerns like thermal runaway. Additionally, repeated charging cycles at high voltages can exacerbate degradation, reducing the battery’s life. Their susceptibility to thermal instability and degradation poses a challenge. As EVs demand more safe, robust and reliable batteries, addressing these challenges becomes essential.

The controlled and precise heat treatment of nickel-rich cathode active materials can greatly contribute to enhance the structural integrity and lifespan of batteries with such chemistries.

The calcination (alternatively called sintering) step is a necessary process step during which the nickel-rich cathode active material (CAM) is heated at a high temperature and under an oxygen-rich environment. During this process, an oxidation reaction takes place, and the desired molecular structure is attained, which will then allow the effective motion of ions and electrons throughout the material. 

Advanced heat treatment technologies are being developed to improve the quality and conditions for the calcination process. The current most-used technology for this process is the roller hearth kiln (RHK). It is capable of attaining the necessary requirements for a successful and effective calcination:  temperature uniformity, a pure and precisely controlled oxygen-rich atmosphere, as well as effective waste management. 

The first important criterion for optimal calcination conditions is temperature uniformity throughout the cross-section of the kiln. This is attained by a careful choice of insulation materials and geometry throughout the different structures within the kiln, allowing the heat to remain within. Uniformity is also obtained by separating the kiln in multiple temperature zones throughout its length, which then allows the entirety of the CAM material going through the furnace, to have a uniform and controlled heating gradient, with little temperature fluctuation.

The atmosphere of the kiln is maintained by isolating it from the exterior air and avoiding contamination, through the use of purge sluices, and effective isolation and sealing technology. Furthermore, controlling the volume of protective gas being blown through the kiln will also contribute to maintaining the proper conditions for the process to take place, as well increasing the efficiency through reduced gas consumption. Keeping a clean and pure atmosphere, atmosphere is key for an effective and complete calcination of the Ni-rich CAM.

Furthermore, the cleanliness of the atmosphere is also tightly related to the waste management of the kiln in which the process takes place. As the cathode material is heated, it releases high amounts of moisture, which could possibly generate unwanted phase changes during the process, resulting in unwanted impurities in the end-product. Therefore, there needs be effective evacuation of any unwanted substances and reaction byproducts from the atmosphere within the kiln.

The thermal process of calcination not only allows the Ni-rich CAM to reach its desired crystal structure, but it can enhance the structural stability and results in improved thermal stability, reduced risk of degradation, and enhanced overall battery performance.

The proper execution of the calcination step has a profound impact on the performance of Ni-rich EV batteries. By enhancing the stability and durability of such batteries, these methods contribute to longer-lasting batteries that require less frequent replacements, making EVs more sustainable in the long run. 

Advanced heat treatment techniques for nickel-rich EV batteries represent a crucial development in the pursuit of more efficient and sustainable electric vehicles. By addressing the inherent challenges of nickel-rich chemistries, these techniques are paving the way for EVs that are not only more powerful and efficient but also safer and more reliable. As the EV market continues to expand, these advancements in battery technology will play a key role in shaping a greener, more sustainable future for transportation.